{"id":1209,"date":"2018-01-20T23:51:34","date_gmt":"2018-01-20T22:51:34","guid":{"rendered":"https:\/\/cosys.chimie.unistra.fr\/?page_id=1209"},"modified":"2026-02-02T09:13:06","modified_gmt":"2026-02-02T08:13:06","slug":"publications","status":"publish","type":"page","link":"https:\/\/cosys.chimie.unistra.fr\/?page_id=1209","title":{"rendered":"Publications"},"content":{"rendered":"

2026<\/strong><\/span><\/h2>\r\n

Thermal Dearomative Rearrangement of \u03b1-(Prop-2-enyl)-\u03b1\u2019-(pyridin-2-yl) Malonate Derivatives towards 4H-Dihydroquinolizines<\/span><\/strong><\/a><\/p>\r\n


\r\n\"\"<\/a><\/p>\r\n

Locquet, P.; Boussalem, N.; Hatey, D.; Grellepois, F.; H\u00e9non, E.; Riguet, E.; Blanc, A. 2026<\/strong>, Org. Lett., ASAP<\/em>.<\/p>\r\n

Pre-Print:<\/strong> 10.26434\/chemrxiv-2025-2p3qw<\/a><\/p>\r\n

2025<\/strong><\/span><\/h2>\r\n

Synergistic Gold-Silicon Catalysis: Unravelling Alkynyl Gold Reactivity and Application to the High-Performance C-Alkynylation of Glycals<\/span><\/strong><\/a><\/p>\r\n

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Pascaretti, M; Starck, E.; Padilla Hernandez, A.; Pertschi, R, Taillier, C.; Blanc, A.; Weibel, J.-M.; Dalla, V.; Pale, P. Chem. Eur. J.<\/em> 2025<\/strong>, e202502027.<\/span><\/p>\r\n

M<\/span><\/strong>erging Enantios<\/strong>elective Lewis Base Organocatalysis and Gold(I) Catalysis: A One-Pot Access to Chiral Fused Polycyclic Compounds<\/strong><\/span><\/a><\/p>\r\n

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Pereira, P.; <\/span>Locquet, P.; Blanc, A.; Grellepois, F.; Riguet, E. J. Org. Chem.<\/em> 2025<\/strong>, 3475\u20133479.<\/span><\/p>\r\n

Pre-Print:<\/strong> 10.26434\/chemrxiv-2024-nrz6q<\/a><\/p>\r\n

Chiral N<\/em>-Alkylfluorenyl-Substituted N-Heterocyclic Carbenes in the Gold(I)-Catalyzed Enantioselective Cycloisomerization of 1,6-Enynes<\/strong><\/span><\/a><\/p>\r\n

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Heinrich, R.; Marie-Rose, G.; Gourlaouen, C.; Pale, P.; Brenner, E.; <\/span>Blanc<\/span>, A. Chem. Eur. J.<\/em> 2025<\/strong>, e202404446.<\/p>\r\n

Pre-print:<\/strong> 10.26434\/chemrxiv-2024-qrnt9<\/a><\/p>\r\n

2024<\/strong><\/span><\/h2>\r\n

CuI<\/sup>-Zeolite Catalysis for Biaryl Synthesis via Homocoupling Reactions of Phenols or Aryl Boronic Acids<\/span><\/strong><\/a><\/p>\r\n

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Di, X.; Tony Garnier, T.; Clerc, A.; Jung, E.; Lherbet, C.; B\u00e9n\u00e9teau, V.; Pale, P.; Chassaing, S. Molecules<\/em> 2024<\/strong>, 29<\/em>, 5552.<\/p>\r\n

Unlocking the Aromatic Cope Rearrangement with Gold(I)<\/span><\/span> Catalysis<\/span><\/span><\/strong><\/a><\/p>\r\n

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Locquet, P.; Rajamani, A.; Pereira, P.; Grellepois, F.; Weibel, J.-M.; H\u00e9non, E.; Riguet, E.; <\/span>Blanc<\/span>, A. ACS Catal. <\/em>2024<\/strong>, 14<\/em>, 18884\u201318895.<\/p>\r\n

Pre-Print:<\/strong> 10.26434\/chemrxiv-2024-6864j<\/a><\/p>\r\n

Gold(I)-Catalyzed Access to 1-Alkynyl C-Glycosides from 1-Silylated Alkynes: An Alternative Paradigm for the Direct and \u03b1-Stereoselective Alkynylation of Glycosides<\/span><\/strong><\/a><\/p>\r\n

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Strack, E.; <\/span>Pascaretti, M.; <\/span>Taillier, C.;<\/span>\u00a0Blanc<\/span>, A.; Dalla, V.;<\/span> Pale<\/span>, P.; Weibel, J.-M. ACS Catal.<\/em> 2024<\/strong>, 14<\/em>, 14863\u201314870.<\/p>\r\n

Gold(I)-Catalyzed Reactions of exo<\/i>-Glycals with Propargyl Esters toward C-1 Alkenyl Spirocyclopropyl Carbohydrates<\/span><\/span><\/strong><\/a><\/p>\r\n

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Lang, M.; <\/span>Walter, S.; <\/span>Hatey, D.;<\/span>\u00a0Blanc<\/span>, A.; Compain, P.;<\/span> Kern<\/span>, N. Org. Lett.<\/em> 2024<\/strong>, 26, 8017\u20138022.<\/p>\r\n

Structural Analysis of Neomycin B and Kanamycin A Binding Aminoglycosides Modifying Enzymes (AME) and Bacterial Ribosomal RNA Derivatives<\/span><\/strong><\/a><\/p>\r\n

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Revillo Imbernon, J.; Weibel, J.-M.; Ennifar, E.; Pr\u00e9vost, G.; Kellenberger, E. <\/span>Mol. Inform.<\/em> 2024<\/strong>, e202300339.<\/p>\r\n

Toward Efficient and Stereoselective Aromatic and Dearomative Cope Rearrangements: Experimental and Theoretical Investigations of \u03b1-Allyl-\u03b1\u2019-Aromatic \u03b3-Lactone<\/strong> Derivatives<\/strong><\/a><\/span><\/p>\r\n

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Mando, M.; Grellepois, F.; Blanc, A.; H\u00e9non, E.; Riguet, E. Chem. Eur. J.<\/em> 2024<\/strong>,\u00a0e202304138.<\/p>\r\n

2023<\/strong><\/span><\/h2>\r\n

Photoactivatable Liposomes for Blue to Deep Red Light-Activated Surface Drug Release: Application to Controlled Delivery of the Antitumoral Drug Melphalan<\/span><\/strong><\/a><\/p>\r\n

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Brion, A.; Chaud, J.; Klimezak, M.; Ohlmann, L., L\u00e9onard, J.; Chassaing, S.; Frisch, B.; Kichler, A.; Heurtault, B.; Specht, A. Bioconjugate Chem.<\/em>, 2023<\/strong>, 34<\/em>, 1304.<\/p>\r\n

Red Light-Responsive Upconverting Nanoparticles for Quantitative and Controlled Release of a Coumarin-Based Prodrug<\/strong><\/a><\/p>\r\n

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Brion, A.; Chaud, J.; L\u00e9onard, J.; Bolze, F.; Chassaing, S.; Frisch, B.; Heurtault, B.; Kichler, A.; Specht, A. Adv. Healthcare Mater.<\/em>, 2023<\/strong>, 12<\/em>, 2201474.<\/p>\r\n

Copper-zeolites Prepared by Solid-state Ion Exchange – Characterization and Evaluation for the Direct Conversion of Methane to Methanol<\/strong><\/a><\/p>\r\n

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Kvande, K.; Prodinger, S.; Schlimpen, F.; Beato, P.; Pale, P.; Chassaing, S.; Svelle, S. Topics in Catalysis<\/em>, 2023<\/strong>, 66<\/em>, 1406.<\/p>\r\n

2022<\/span><\/strong><\/span><\/h2>\r\n

A Gold(I)-Catalysed Approach towards Harmalidine, an Elusive Alkaloid from Peganum Harmala<\/strong><\/a><\/p>\r\n

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Miaskiewicz, S.; Weibel, J.-M.; Pale, P.; Blanc, A. RSC Advances<\/em>, 2022<\/strong>, 12<\/em>, 26966.<\/p>\r\n

Dinuclear Silver(I) and Gold(I) Complexes with Chiral Oxazoline-NHC Ligands<\/strong><\/a><\/p>\r\n

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Hoffmann, M.; Dargorne, S.; Pale, P.; Blanc, A.; de Fr\u00e9mont, P. J. Organomet. Chem.<\/em>, 2022<\/strong>, 979<\/em>, 122507.<\/p>\r\n

From A3\/KA2 to AYA\/KYA Multicomponent Coupling Reactions with Terminal Ynamides as Alkyne Surrogates \u2013 a Direct, Green Route to \u03b3-Amino-ynamides<\/strong><\/a><\/p>\r\n

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Schlimpen, F.; <\/span>Ast<\/span>, T.; B\u00e9n\u00e9teau, V.; Pale, P.; Chassaing, S. Green Chem.<\/em> 2022<\/strong>, 6467.<\/p>\r\n

Rhazinilam-Leuconolam Family of Natural Products: a Half Century of Total Synthesis<\/strong><\/a><\/p>\r\n

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Sirindil, F.; Weibel, J.-M.; Pale, P.; Blanc, A. Nat. Prod. Rep.<\/em> 2022<\/strong>, 39<\/em>, 1574.<\/p>\r\n

Targeted Modifications of Neomycin and Paromomycin: Towards Resistance\u2013free Antibiotics?<\/strong><\/a><\/p>\r\n

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Obszynski, J.; Loidon, H.; Blanc, A.; Weibel, J.-M.; Pale, P. Bioorg. Chem.<\/em>, 2022<\/strong>, 126<\/em>, 105824.<\/p>\r\n

trans<\/em>-Dichlorobis(XPhos)Palladium(II) Precatalyst for Suzuki-Miyaura Cross-Coupling Reactions of Aryl\/Vinyl Sulfonates\/Halides: Scope, Mechanistic Study and Synthetic Applications<\/strong><\/a><\/p>\r\n

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Sirindil, F.; Pertschi, R.; Naulin, E.; Hatey, D.; Weibel, J.-M.; Pale, P.; Blanc, A.; ACS Omega<\/em> 2022<\/strong>, 1186.<\/p>\r\n

2021<\/strong><\/span><\/h2>\r\n

\u03b1-Tertiary Propargylamine Synthesis via KA2-Type Coupling Reactions under Solvent-Free CuI-Zeolite Catalysis<\/strong><\/a><\/p>\r\n

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Schlimpen, F.; <\/span>Pla\u00e7ais, C.; Starck, E.<\/span>; B\u00e9n\u00e9teau, V.; Pale, P.; Chassaing, S. J. Org. Chem<\/em>. 2021<\/strong>, 86<\/span><\/em>, 16593<\/span>.<\/p>\r\n

Two-Photon Sensitive Coumarinyl Photoremovable Protecting Groups with Rigid Electron-Rich Cycles Obtained by Domino Reactions Initiated by a 5-exo<\/i>-Dig Cyclocarbopalladation<\/span><\/strong><\/a><\/p>\r\n

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Chaud, J.; Morville, C.; Bolze, F.; Garnier, D.;\u00a0 Chassaing, S.; Blond, G.; Specht, A. Org. Lett.<\/i><\/span> 2021<\/span><\/strong>, 23<\/em><\/span>,<\/span> 7580.<\/span><\/p>\r\n

Computational Study of Benzosultam formation via Gold(I)-Catalyzed Ammoniumation \/ Nucleophilic Substitution Reaction<\/strong><\/a><\/p>\r\n

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Pertschi, R.; de Aguirre, A.; Pale, P.; Blanc, A.; Poblador Bahamonde, A. I. Helv. Chim. acta<\/em>. 2021<\/strong>, 104<\/em>, e2100133.<\/p>\r\n

Gold(I)-Catalyzed Divergent and Diastereoselective Synthesis of Azepines by Ammoniumation\/Ring-Expansion Reactions<\/strong><\/a><\/p>\r\n

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Pertschi, R.; Miaskiewicz, S.; Kern, N.; Weibel, J.-M.; Pale, P.;<\/u> Blanc, A. Chem. Catal.<\/em> 2021<\/strong>, 1<\/em>, 129.<\/p>\r\n

Recent Advances in the Synthesis and Applications of Chiral Gold(III) Complexes<\/strong><\/a><\/p>\r\n

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Jouhannet, R.; Dagorne, S.; Blanc, A.; de Fr\u00e9mont, P. Chem.\u2013Eur. <\/em>J.<\/em> 2021<\/strong>, 27<\/em>, 9218.<\/p>\r\n

A Coumarin-Based Analogue of Thiacetazone as Dual Covalent Inhibitor and Potential Fluorescent Label of HadA in Mycobacterium tuberculosis<\/i><\/span><\/strong><\/a><\/p>\r\n

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Farjallah, A.; <\/span>Chiarelli, L. R.; <\/span>Forbak, M.; <\/span>Degiacomi, G.; <\/span>Danel, M.; <\/span>Goncalves, F.; <\/span>Carayon, C.; <\/span>Seguin, C.; <\/span>Fumagalli, M.; <\/span>Z\u00e1horszk\u00e1, M.; <\/span>Vega, E. <\/span>Abid, S.; <\/span>Grzegorzewicz, A.; <\/span>Jackson, M.; <\/span>Antonio Peixoto, A.; <\/span>Kordul\u00e1kov\u00e1, J.; <\/span>Pasca, M. R.; <\/span>Lherbet, C.; <\/span>Chassaing, S. ACS Infect. Dis.<\/em> 2021<\/strong>, 7<\/em>, 552.<\/span><\/p>\r\n

2020<\/strong><\/span><\/h2>\r\n

Comparative Enantioseparation of Chiral 4,4\u2019-Bipyridine Derivatives on Coated and Immobilized Amylose-Based Chiral Stationary Phases<\/span><\/span><\/strong><\/a><\/p>\r\n

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Peluso, P.; Sechi, B.; Lai, G.; Dess\u00ec, A.; Dallocchio, R.; Cossu, S.; Aubert, E.; Weiss, R.; Patrick Pale, P.; Mamane, V.; Bezhan Chankvetadze, B. J. Chromatogr. A<\/em> 2020<\/strong>, 1625<\/em>, 461303.<\/p>\r\n

Noncovalent Interactions in High-Performance Liquid Chromatography Enantioseparations on Polysaccharide-Based Chiral Selectors<\/a><\/span><\/strong><\/span><\/p>\r\n

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Peluso, P.; Mamane, V.; Dallocchio, R.; Dess\u00ec, A.; Cossu, S. J. Chromatogr. A<\/em> 2020<\/strong>, 1623<\/em>, 461202.<\/p>\r\n

Halogen bond in separation science: overview, concepts and perspectives<\/span><\/span><\/strong><\/a><\/p>\r\n

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Peluso, P.; Mamane, V.; Dess\u00ec, A.; Dallocchio, R.; Aubert, E.; Gatti, C.; Mangelings, D.; Sergio Cossu, S. J. Chromatogr. A<\/em> 2020<\/strong>, 1616<\/em>, 460788.<\/p>\r\n

Rational Design, Synthesis, Characterization and Evaluation of Iodinated 4,4\u2032-Bipyridines as New Transthyretin Fibrillogenesis Inhibitors<\/span><\/span><\/strong><\/a><\/p>\r\n

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Dess\u00ec, A.; Peluso, P.; Dallocchio, R.; Weiss, R.; Andreotti, G.; Allocca, M.; Aubert, E.; Pale, P.; Mamane, V.; Cossu, S. Molecules<\/em> 2020<\/strong>, 25<\/em>, 2213.<\/p>\r\n

Synthesis, Characterization, and Catalytic Activity of Chiral NHC Platinum(II) Pyridine Dihalide Complexes<\/span><\/span><\/strong><\/a><\/p>\r\n

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Pertschi, R.; Hatey, D.; Pale, P.; de Fr\u00e9mont, P.; Blanc, A. Organometallic <\/em>2020<\/strong>, 39<\/span><\/em>, <\/span>804\u2013812<\/span>.<\/p>\r\n

Evans\u2010Chan\u2010Lam\u2010Type Azidation and One\u2010Pot CuAAC under CuI\u2010Zeolite Catalysis<\/strong><\/span><\/a><\/p>\r\n

\"\"<\/p>\r\n

Clerc, A; B\u00e9n\u00e9teau, V; Pale, P; Chassaing, S. Chem. Cat. Chem<\/em>. 2020<\/strong>, 12, 2060\u20132065.<\/p>\r\n

201<\/strong>9<\/strong><\/span><\/h2>\r\n

Chiral Chalcogen Bond Donors Based on the 4,4′-Bipyridine Scaffold<\/strong><\/a><\/span><\/p>\r\n

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Weiss, R.; Aubert, E.; Peluso, P.; Cossu, S.; Pale, P.; Mamane, V. Molecules<\/em> 2019, 24, 4484.<\/p>\r\n

Synthesis of Indolizine and Pyrrolo[1,2-a]azepine Derivatives via a Gold(I)\u2013Catalyzed 3-Step Cascade<\/span><\/strong><\/a><\/p>\r\n

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Sirindil, F.; Golling, S.; Lamare, R.; Weibel, J. M.; Pale, P.; Blanc, A. Org. Lett. <\/em>2019<\/strong>, 21<\/em>, 8997\u20139000.<\/p>\r\n

Benzosultam Synthesis by Gold(I)-Catalyzed Ammonium Formation\/Nucleophilic Substitution<\/strong><\/span><\/a><\/p>\r\n

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Pertschi, R.; Weibel, J. M.; Pale, P.; Blanc, A. Org. Lett. <\/em>2019<\/strong>, 21<\/em>, 5616\u20135620.<\/p>\r\n

Borylation and rearrangement of alkynyloxiranes\u00a0: a stereospecific route to substituted \u03b1-enynes.<\/strong><\/span><\/a><\/p>\r\n

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Fuentespina R. P.; Garcia de la Cruz, J. L.; Durin, G.; Mamane, V.; Weibel, J.-M.; Pale, P. Beilstein J. Org. Chem. <\/i>2019<\/b>, 15<\/i>, 1416\u20131424.<\/p>\r\n

Total Synthesis of Rhazinilam through Gold-Catalyzed Cycloisomerization-Sulfonyl Migration & Palladium-Catalyzed Suzuki-Miyaura Coupling of Pyrrolyl Sulfonates<\/span><\/strong><\/span><\/a><\/p>\r\n

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Sirindil, F.; Weibel, J. M.; Pale, P.; Blanc, A. Org. Lett. <\/em>2019<\/strong>, 21<\/em>, 5542\u20135546.<\/p>\r\n

When Gold Cations Meet Polyoxometalates (Review)<\/strong><\/span><\/span><\/a><\/p>\r\n

\"\"<\/a><\/p>\r\n

Blanc, A.; de Fr\u00e9mont, P. Chem.\u2013Eur. J.\u00a0<\/em>2019<\/strong>, 25<\/em>, 9553\u20139567.<\/p>\r\n

201<\/strong>8<\/strong><\/span>
\r\n<\/strong><\/span><\/span><\/h2>\r\n

Vinyl Nosylates as Partner in Copper and Silver Co-Catalyzed Sonogashira Cross-Coupling Reactions<\/span><\/strong><\/span><\/a><\/p>\r\n

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Cheval, N. P.; Hoffmann, B.; Dikova, A.; Sirindil, F., Blanc, A.; Weibel, J.-M.; Pale, P. Tetrahedron<\/em> 2018<\/strong>, 74<\/em>, 7111\u20137119.<\/p>\r\n

Enantioseparation of fluorinated 3-arylthio-4,4′-bipyridines: Insights into chalcogen and \u03c0-hole bonds in high-performance liquid chromatography<\/strong><\/span><\/a><\/p>\r\n

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Peluso, P.; Gatti, C.; Dessi, A.; Dallocchio, R.; Weiss, R.; Aubert, E.; Pale, P.; Cossu, S.; Mamane, V. J. Chromatogr. A<\/em>, 2018<\/strong>, 119\u2013129.<\/p>\r\n

Synthesis, Characterization and Catalytic Activity of NHC Gold(I) Polyoxometalate Complexes<\/span><\/strong><\/a><\/p>\r\n

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Sirindil, F.; Nolan, S. P.; Dagorne, S.; Pale, P.; Blanc, A.; de Fr\u00e9mont, P. Chem.\u2013Eur. <\/em>J.<\/em> 2018<\/strong>, 24<\/em>, 12630\u201312637.<\/p>\r\n

Regioselective Synthesis of Indene from 3-Aryl Propargylic gem-Dipivalates Catalyzed by N<\/em>-Heterocyclic Carbene Gold(I) Complexes<\/strong><\/span><\/a><\/p>\r\n

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Hueber, D.; Teci, M.; Brenner, E.; Matt, D.; Weibel, J.-M.; Pale, P.; Blanc, A. Adv. <\/em>Synth. Catal.<\/em> 2018<\/strong>, 360<\/em>, 2453\u20132459.<\/p>\r\n

Copper(I)-USY as a Ligand-Free and Recyclable Catalyst for Ullmann-Type O-, N-, S-, and C-Arylation Reactions: Scope and Application to Total Synthesis<\/strong><\/a><\/span>
\r\n<\/em><\/p>\r\n

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Garnier, T.; Danel, M.; Magne, V.; Pujol, A.; Beneteau, V.; Pale, P.; Chassaing, S. J. Org. Chem.<\/em> 2018<\/strong>, 83<\/em>, 6408\u20136422.<\/p>\r\n

Green Catalysts Based on Zeolites for Heterocycle Synthesis (Review)<\/strong><\/a><\/span>
\r\n<\/em><\/p>\r\n

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Chassaing, S.; Beneteau, V.; Pale, P. Curr. Opin. Green Sustain. Chem.<\/em> 2018<\/strong>, 10<\/em>, 35\u201339.<\/p>\r\n

Silver\u2013Promoted Coupling Reactions (Book Chapter)<\/strong><\/span>
\r\n<\/em><\/p>\r\n

\"\"<\/p>\r\n

Weibel, J.-M.; Blanc, A.; Pale, P. Chapter 3.5.13<\/u> in Synthesis Knowledge Updates Vol. 3 Compounds of Groups 12 and 11<\/em>, 2018\/1, pp 1\u2013109.<\/p>\r\n

2017<\/strong><\/span><\/h2>\r\n

Synthesis of 2-Carboxylated Aza-Ring Derivatives through \u03b1-Monohalogenation\/Ring-Contraction of N<\/em>-Sulfonyl Lactams<\/span><\/span><\/strong><\/span><\/a><\/p>\r\n

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Sirindil, F.; Miaskiewicz, S.; Kern, N.; Lalaut, A.; Felten, A.-S.; Weibel, J.-M.; Pale, P.; Blanc, A. Tetrahedron<\/i> 2017<\/b>, 73<\/i>, 5096\u20135106.<\/div>\r\n
\u00a0<\/div>\r\n
Metal Confinement through N-(9-Alkyl)fluorenyl Substituted N-Heterocyclic Carbenes and its Consequences in Gold-Catalysed Reactions Involving Enynes<\/span><\/span><\/strong><\/a><\/div>\r\n
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Teci, M.; Hueber, D.; Pale, P.; Toupet, L.; Blanc, A.; Brenner, E.; D. Matt, Chem.\u2013Eur. J.<\/em> 2017<\/strong>, 23<\/em>, 7809\u20137818.<\/p>\r\n<\/div>\r\n<\/div>\r\n<\/div>\r\n

Gold (I)-Catalyzed Cascade: Synthesis of 2, 5-Disubstituted Pyrroles from N<\/em>-Sulfonyl-2-(1-ethoxypropargyl) azetidines through Cyclization\/Nucleophilic Substitution\/Elimination<\/strong><\/span><\/a><\/p>\r\n

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Pertschi, R.; Miaskiewicz, S.; Weibel, J.-M.; Pale, P.; Blanc, A. Synthesis<\/i> 2017<\/b>, 49<\/i>, 4151\u20134162.<\/div>\r\n
\u00a0<\/div>\r\n<\/div>\r\n<\/div>\r\n

Zeolite-Based Organic Synthesis (ZeoBOS) of Acortatarin A: First Total Synthesis Based on Native and Metal-Doped Zeolite-Catalyzed Steps<\/strong><\/span><\/a><\/p>\r\n

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Wimmer, E.; Borgh\u00e8se, S.; Blanc, A.; B\u00e9n\u00e9teau, V.; Pale, P.\u00a0Chem.\u2013Eur. J.<\/em> 2017<\/b>, 23<\/i>, 1484\u20131489.<\/p>\r\n

Chan\u2013Lam-Type C\u2013N Cross-Coupling Reactions under Base- and Ligand-Free CuI<\/sup>-Zeolite Catalysis<\/strong><\/span><\/a><\/p>\r\n

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Garnier, T.; Sakly, R.; Danel, M.; Chassaing, S.; Pale, P. Synthesis,<\/em> 2017<\/b>, 49<\/i>, 1223\u20131230.<\/div>\r\n

2016<\/strong><\/span><\/h2>\r\n

Silver & Gold Routes to Furans<\/span> and Benzofurans (Review)<\/strong><\/span><\/span><\/a><\/p>\r\n

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Blanc, A.; B\u00e9n\u00e9teau, V.; Weibel, J.-M.; Pale, P. Org. <\/em>Biomol. Chem.<\/em> 2016<\/strong>, 14<\/em>, 9184\u20139205.<\/p>\r\n

Gold(I)-Catalyzed N<\/em>-Desulfonylative Amination versus N<\/em>-to-O<\/em> 1,5-Sulfonyl Migration: A Versatile Approach to 1-Azabicycloalkanes<\/strong><\/span><\/a><\/p>\r\n

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Miaskiewicz, S.; Gaillard, B.; Kern, N.; Weibel, J.-M.; Pale, P.; Blanc, A. Angew. Chem. Int. Ed.<\/i> 2016<\/b>, 55<\/i>, 9088\u20139092.<\/div>\r\n<\/div>\r\n<\/div>\r\n
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Aryl and Heteroaryl Nosylates as Stable and Cheap Partners for Suzuki\u2013Miyaura Cross-Coupling Reactions<\/strong><\/span><\/a><\/p>\r\n

\"Tetrahedron<\/a><\/p>\r\n<\/div>\r\n

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Dikova, A.; Cheval, N. P.; Blanc, A.; Weibel, J.-M.; Pale, P. Tetrahedron<\/i> 2016<\/b>, 72<\/i>, 1960\u20131968.<\/div>\r\n
\u00a0<\/div>\r\n<\/div>\r\n<\/div>\r\n
\r\n

Gold(I)-Catalyzed Cyclization\/Nucleophilic Substitution of 1-(N<\/i>-Sulfonylazetidin-2-yl) Ynones into N<\/i>-Sulfonylpyrrolin-4-ones<\/span><\/strong><\/span><\/a><\/p>\r\n

\"\"<\/a><\/p>\r\n

\r\n
\r\n
\r\n
\r\n
\r\n
Miaskiewicz, S.; Weibel, J.-M.; Pale, P.; Blanc, A. Org. Lett.<\/i> 2016<\/b>, 18<\/i>, 844\u2013847.<\/div>\r\n
\u00a0<\/div>\r\n<\/div>\r\n<\/div>\r\n<\/div>\r\n<\/div>\r\n<\/div>\r\n

When CuAAC ‘Click Chemistry’ Goes Heterogeneous (Review)<\/span><\/a>
\r\n<\/strong><\/span><\/p>\r\n<\/div>\r\n

\"Catal<\/a><\/p>\r\n

\r\n
\r\n
Chassaing, S.; B\u00e9n\u00e9teau, V.; Pale, P. Catal. Sci. & Technol.<\/i> 2016<\/b>, 6<\/i>, 923\u2013957.<\/div>\r\n
\u00a0<\/div>\r\n<\/div>\r\n<\/div>\r\n

2015<\/strong><\/span><\/h2>\r\n

Handy Protocols using Vinyl Nosylates in Suzuki\u2013Miyaura Cross-Coupling Reactions<\/strong><\/span><\/a><\/p>\r\n

\"Adv<\/a><\/p>\r\n

\r\n
\r\n
Dikova, A.; Cheval, N. P.; Blanc, A.; Weibel, J.-M.; Pale, P. Adv. <\/em>Synth. Catal.<\/em><\/i> 2015<\/b>, 357<\/i>, 4093\u20134100.<\/div>\r\n<\/div>\r\n<\/div>\r\n

CuI<\/sup>\u2013USY as a Ligand-Free and Recyclable Catalytic System for the Ullmann-Type Diaryl Ether Synthesis<\/strong><\/span><\/a><\/p>\r\n

\"Org<\/a><\/p>\r\n

Magn\u00e9, V.; Garnier, T.; Danel, M.; Pale, P.; Chassaing, S. Org. Lett.,<\/em> 2015<\/strong> 17<\/em>, 4494\u20134497.<\/p>\r\n

Polyoxometalate-Gold(I)\/H+ Complexes: Air-Stable, Efficient, Polyvalent, and Bifunctional Catalysts<\/strong><\/span><\/a><\/p>\r\n

\"Organometallics,<\/a><\/p>\r\n

Hueber, D.; Hoffmann, M.; de Fr\u00e9mont, P.; Pale, P.; Blanc, A. Organometallics<\/em> 2015<\/strong>, 34<\/em>, 5065\u20135072.<\/p>\r\n

Easy, Green and Safe Carbonylation Reactions through Zeolite-Catalyzed Carbon Monoxide Production from Formic Acid<\/strong><\/span><\/a><\/p>\r\n

\"Adv<\/a><\/p>\r\n

Losch, P.; Felten, A.-S.; Pale, P. Adv. Synth. Catal.<\/em> 2015<\/strong>, 357<\/em>, 2931\u20132938.<\/p>\r\n

Assigning Regioisomeric or Diastereoisomeric Relations of Problematic Trisubstituted Double-Bonds through Heteronuclear 2D Selective J<\/em>-Resolved NMR Spectroscopy<\/strong><\/span><\/a><\/p>\r\n

\"RSC<\/a><\/p>\r\n

Hoffmann, M.; Miaskiewicz, S.; Weibel, J.-M.; Pale, P.; Blanc, A. RCS Advances<\/em> 201<\/strong>5<\/strong>, 5<\/em>, 37138\u201337148.<\/p>\r\n

2014<\/strong><\/span><\/h2>\r\n

Zeo-Click Synthesis: Copper-Zeolite-Catalyzed Synthesis of Ynamides<\/span><\/a><\/strong><\/p>\r\n

Harkat, H.; Borgh\u00e8se, S.; Nigris, M. D.; Kiselev, S.; B\u00e9n\u00e9teau, V.; Pale, P. Adv. <\/em>Synth. Catal.<\/em> 2014<\/strong>, 356<\/em>, 3842\u20133848.<\/p>\r\n

Robust Synthesis of N<\/i>-Sulfonylazetidine Building Blocks via Ring Contraction of \u03b1-Bromo N<\/i>-Sulfonylpyrrolidinones<\/strong><\/span><\/a><\/p>\r\n

Kern, N.; Felten, A.-S.; Weibel, J.-M.; Pale, P.; Blanc, A. Org. <\/em>Lett.<\/em> 2014<\/strong>, 16<\/em>, 6104\u20136107.<\/p>\r\n

Copper(II) bromide as an efficient catalyst for acetal to bisarylmethyl ether interconversion<\/a><\/span><\/strong><\/p>\r\n

Mezaache, R.; Harkat, H.; Obszynski, J.; Benkouider, A.; Blanc, A.; Weibel, J.-M.; Pale, P. Tetrahedron Lett.<\/em> 2014<\/strong>, 55<\/em>, 7167\u20137171.<\/p>\r\n

Chemoenzymatic routes to cyclopentenols: the role of protecting groups on stereo- and enantioselectivity<\/strong><\/a><\/span><\/p>\r\n

Specklin, S.; Dikova, A.; Blanc, A.; Weibel, J.-M.; Pale, P. Tetrahedron Lett.<\/em> 2014<\/strong>, 55<\/em>, 6987\u20136991.<\/p>\r\n

Short and efficient route toward \u03b1-substituted N<\/em>-arylazetidines from\u00a0acetanilides via Mitsunobu reaction<\/strong><\/span><\/a><\/p>\r\n

Kern, N.; Hoffmann, M.; Weibel, J.-M.; Pale, P.; Blanc, A. Tetrahedron<\/em> 2014<\/strong>, 70<\/em>, 5519\u20135531.<\/p>\r\n

Synthesis, Characterization, and Catalytic Activity of Alcohol-Functionalized NHC Gold(I\/III)<\/span> Complexes<\/strong><\/span><\/a><\/p>\r\n

Jacques, B.; Hueber, D.; Hameury, S.; Braunstein, P.; Pale, P.; Blanc, A.; de Fr\u00e9mont, P. Organometallics<\/em> 2014<\/strong>, 33<\/em>, 2326\u20132335.<\/p>\r\n

Inorganic\u2013Organic Heteropolyacid\u2013Gold(I) Hybrids: Structures and Catalytic Applications<\/span><\/strong><\/span><\/a><\/p>\r\n

Hueber, D.; Hoffmann, M.; Louis, B.; Pale, P.; Blanc, A. Chem. – Eur. J.<\/em> 2014<\/strong>, 20<\/em>, 3903\u20133907.<\/p>\r\n

Gold(I)\/(III)-Catalyzed Rearrangement of Divinyl Ketones and Acyloxyalkynyloxiranes into Cyclopentenones<\/span><\/strong><\/a><\/p>\r\n

\u00a0Hoffmann, M.; Weibel, J.-M.; de Fr\u00e9mont, P.; Pale, P.; Blanc, A. Org. Lett.<\/em> 2014<\/strong>, 16<\/em>, 908\u2013911.<\/p>\r\n

2013<\/strong><\/span><\/h2>\r\n

Gold(I)-catalyzed formation of furans from \u03b3-acyloxyalkynyl ketones<\/span><\/strong><\/a><\/p>\r\n

Hoffmann, M.; Miaskiewicz, S.; Weibel, J.-M.; Pale, P.; Blanc, A. Beilstein J. Org. Chem.<\/em> 2013<\/strong>, 9<\/em>, 1774\u20131780.<\/p>\r\n

Diels\u2013Alder Reaction between Isoprene and Methyl Acrylate over Different Zeolites: Influence of Pore Topology and Acidity<\/span><\/strong><\/a><\/p>\r\n

Bernardon, C.; Louis, B.; B\u00e9n\u00e9teau, V.; Pale, P. ChemplusChem<\/em> 2013<\/strong>, 78<\/em>, 1134\u20131141.<\/p>\r\n

Synthesis, Characterization, and Catalytic Activity of Cationic NHC Gold(III) Pyridine Complexes<\/span><\/strong><\/a><\/p>\r\n

Orbisaglia, S.; Jacques, B.; Braunstein, P.; Hueber, D.; Pale, P.; Blanc, A.; de Fr\u00e9mont, P. Organometallics<\/em> 2013<\/strong>, 32<\/em>, 4153\u20134164.<\/p>\r\n

\u00a0<\/h5>\r\n

Vinyl Nosylates: An Ideal Partner for Palladium-Catalyzed Cross-Coupling Reactions<\/span><\/a><\/strong><\/p>\r\n

Cheval, N. P.; Dikova, A.; Blanc, A.; Weibel, J.-M.; Pale, P. Chem. – Eur. J.<\/em> 2013<\/strong>, 19<\/em>, 8765\u20138768.<\/p>\r\n

Electrophilic chlorination of arenes with trichloroisocyanuric acid over acid zeolites<\/a><\/strong><\/span><\/p>\r\n

Mendon\u00e7a, G. F.; Bastos, A. R.; Boltz, M.; Louis, B.; Pale, P.; Esteves, P. M.; de Mattos, M. C. S. Appl. <\/em>Catal. Gen.<\/em> 2013<\/strong>, 460-461<\/em>, 46\u201351.<\/p>\r\n

Well-defined silica-supported molybdenum nitride species: silica<\/span> grafting triggers alkyne metathesis<\/span> activity<\/strong><\/span><\/span><\/a><\/p>\r\n

Genelot, M.; Cheval, N. P.; Vitorino, M.; Berrier, E.; Weibel, J.-M.; Pale, P.; Mortreux, A.; Gauvin, R. M. Chem. Sci.<\/em> 2013<\/strong>, 4<\/em>, 2680\u20132685.<\/p>\r\n

Silver-zeolite catalysed solvent free synthesis of (spiro)ketals<\/span><\/strong><\/a><\/p>\r\n

Borgh\u00e8se, S.; Drouhin, P.; B\u00e9n\u00e9teau, V.; Louis, B.; Pale, P. Green Chem.<\/em> 2013<\/strong>, 15<\/em>, 1496\u20131500.<\/p>\r\n

Gold(I)-Catalyzed Rearrangement of N<\/i>-Aryl 2-Alkynylazetidines to Pyrrolo[1,2-a<\/i>]indoles<\/span><\/a><\/strong><\/p>\r\n

Kern, N.; Hoffmann, M.; Blanc, A.; Weibel, J.-M.; Pale, P. Org. <\/em>Lett.<\/em> 2013<\/strong>, 15<\/em>, 836\u2013839.<\/p>\r\n

2012<\/strong><\/span><\/h2>\r\n

Silver(I)-Catalyzed Deprotection of p<\/i>-Methoxybenzyl Ethers: A Mild and Chemoselective Method<\/span><\/strong><\/a><\/p>\r\n

Kern, N.; Dombray, T.; Blanc, A.; Weibel, J.-M.; Pale, P. J. Org. Chem.<\/em> 2012<\/strong>, 77<\/em>, 9227\u20139235.<\/p>\r\n

Green route for the chlorination of nitrobenzene<\/strong><\/span><\/a><\/p>\r\n

Boltz, M.; de Mattos, M. C. S.; Esteves, P. M.; Pale, P.; Louis, B. Appl. Catal. Gen.<\/em> 2012<\/strong>, 449<\/em>, 1\u20138.<\/p>\r\n

Vinyl triflates derived from 1,3-dicarbonyl compounds and analogs: access and applications to organic synthesis (Review)<\/strong><\/span><\/a><\/p>\r\n

Chassaing, S.; Specklin, S.; Weibel, J.-M.; Pale, P. Tetrahedron<\/em> 2012<\/strong>, 68<\/em>, 7245\u20137273.<\/p>\r\n

Coinage Metals-Catalyzed Cascade Reactions of Aryl Alkynylaziridines: Silver(I)-Single vs Gold(I)-Double Cyclization<\/a><\/span><\/strong><\/p>\r\n

Kern, N.; Blanc, A.; Miaskiewicz, S.; Robinette, M.; Weibel, J.-M.; Pale, P. J. Org. <\/em>Chem.<\/em> 2012<\/strong>, 77<\/em>, 4323\u20134341.<\/p>\r\n

Scandium(III)-Zeolites as New Heterogeneous Catalysts for Imino-Diels\u2013Alder Reactions<\/span><\/strong><\/span><\/a><\/p>\r\n

Olmos, A.; Louis, B.; Pale, P. Chem. – Eur. J.<\/em> 2012<\/strong>, 18<\/em>, 4894\u20134901.<\/p>\r\n

Vinyl and Aryl Sulfonates: Preparations and Applications in Total Synthesis (Review)<\/span><\/strong><\/p>\r\n

Chassaing, S.; Specklin, S.; Weibel, J.-M.; Pale, P.\u00a0 Curr. Org. Synth.<\/em> 2012<\/strong>, 9, 806\u2013827.<\/p>\r\n

2011<\/strong><\/span><\/h2>\r\n

Br\u00f8nsted acid sites in metal-containing solid acids: from quantification to molecular design of new catalysts\/silver(I<\/small>)-polyoxometalates<\/strong> <\/span><\/a><\/p>\r\n

Borgh\u00e8se, S.; Blanc, A.; Pale, P.; Louis, B. Dalton Trans.<\/em> 2011<\/strong>, 40<\/em>, 1220\u20131223.<\/p>\r\n

Copper(II) bromide as efficient catalyst for silyl- to bisarylmethyl ethers interconversion (transprotection)<\/span><\/strong><\/a><\/p>\r\n

Specklin, S.; Gallier, F.; Mezaache, R.; Harkat, H.; Dembel\u00e9, Y. A.; Weibel, J.-M.; Blanc, A.; Pale, P. Tetrahedron Lett.<\/em> 2011<\/strong>, 52<\/em>, 5820\u20135823.<\/p>\r\n

\u00a0<\/h5>\r\n

Design of silver(I)-heteropolyacids: toward the molecular control of reactivity in organic chemistry<\/span><\/a><\/strong><\/p>\r\n

Borgh\u00e8se, S.; Louis, B.; Blanc, A.; Pale, P. Catal. Sci. Technol.<\/em> 2011<\/strong>, 1<\/em>, 981\u2013986.<\/p>\r\n

Rational Design of Microporous and Mesoporous Solids for Catalysis: From the Molecule to the Reactor<\/span><\/span><\/strong><\/a><\/p>\r\n

Louis, B.; Laugel, G.; Pale, P.; Pereira, M. M. ChemCatChem<\/em> 2011<\/strong>, 3<\/em>, 1263\u20131272.<\/p>\r\n

Gold(I<\/small>)-catalyzed rearrangement of aryl alkynylaziridines to spiro[isochroman-4,2\u2032-pyrrolines]<\/strong><\/span><\/a><\/p>\r\n

Kern, N.; Blanc, A.; Weibel, J.-M.; Pale, P. Chem. Commun.<\/em> 2011<\/strong>, 47<\/em>, 6665\u20136667.<\/p>\r\n

Scandium(III) Zeolites as New Heterogeneous Catalysts: [4+2]Cyclocondensation of in situ Generated Aryl Imines with Alkenes<\/strong><\/span><\/a><\/p>\r\n

Olmos, A.; Sommer, J.; Pale, P. Chem. – Eur. J.<\/em> 2011<\/strong>, 17<\/em>, 1907\u20131914.<\/p>\r\n

Amino-benzosuberone: A novel warhead for selective inhibition of human aminopeptidase-N\/CD13<\/a><\/span><\/strong><\/span><\/p>\r\n

Albrecht, S.; Al-Lakkis-Wehbe, M.; Orsini, A.; Defoin, A.; Pale, P.; Salomon, E.; Tarnus, C.; Weibel, J.-M. Bioorg. <\/em>Med. Chem.<\/em> 2011<\/strong>, 19<\/em>, 1434\u20131449.<\/p>\r\n

2010<\/strong><\/span><\/h2>\r\n

Gold(I)-Catalyzed Cycloisomerization of \u03b2-Alkynylpropiolactones to Substituted \u03b1-Pyrones<\/span><\/a><\/strong><\/p>\r\n

Dombray, T.; Blanc, A.; Weibel, J.-M.; Pale, P. Org. Lett.<\/em> 2010<\/strong>, 12<\/em>, 5362\u20135365.<\/p>\r\n

Zeo-Click Chemistry: Copper(I)\u2013Zeolite-Catalyzed Cascade Reaction; One-Pot Epoxide Ring-Opening and Cycloaddition<\/span><\/strong><\/a><\/p>\r\n

Boningari, T.; Olmos, A.; Reddy, B. M.; Sommer, J.; Pale, P. Eur. J. Org. Chem.<\/em> 2010<\/strong>, 2010<\/em>, 6338\u20136347.<\/p>\r\n

Copper(I)-Zeolites as New Heterogeneous and Green Catalysts for Organic Synthesis<\/a><\/strong><\/span><\/p>\r\n

Kuhn, P.; Louis, B.; Sommer, J.; Pale, P. Synthesis<\/em> 2010<\/strong>, 1557\u20131567.<\/p>\r\n

Zeo-click synthesis: CuI<\/sup>-zeolite-catalyzed one-pot two-step synthesis of triazoles from halides and related compounds<\/span><\/strong><\/a><\/p>\r\n

B\u00e9n\u00e9teau, V.; Olmos, A.; Boningari, T.; Sommer, J.; Pale, P. Tetrahedron Lett.<\/em> 2010<\/strong>, 51<\/em>, 3673\u20133677.<\/p>\r\n

Metal-doped Zeolites as Green Catalysts for Organic Synthesis<\/a><\/strong><\/span><\/p>\r\n

Chassaing, S.; Alix, A.; Olmos, A.; Keller, M.; Sommer, J.; Pale, P. Z. Naturforsch. B<\/i><\/span> 2010<\/span><\/strong>, 65, 783\u2013790.<\/p>\r\n

Gold(I)-Catalyzed Tandem Rearrangement\u2013Nucleophilic Substitution of \u03b1-Acetoxy Alkynyl Oxiranes or Aziridines: Efficient Approach to Furans and Pyrroles<\/span><\/a><\/strong><\/span><\/p>\r\n

Blanc, A.; Alix, A.; Weibel, J.-M.; Pale, P. Eur. J. Org. Chem.<\/em> 2010<\/strong>, 2010<\/em>, 1644\u20131647.<\/p>\r\n

Transformations of N<\/em>-acylaziridines catalysed by support-based silica and alumina: Mechanistic elucidation<\/strong><\/a><\/span><\/p>\r\n

Besbes, N.; Jellali, H.; Pale, P.; Srasra, E.; Efrit, M. L. Comptes Rendus Chim.<\/em> 2010<\/strong>, 13<\/em>, 358\u2013364.<\/p>\r\n\r\n","protected":false},"excerpt":{"rendered":"

2026 Thermal Dearomative Rearrangement of \u03b1-(Prop-2-enyl)-\u03b1\u2019-(pyridin-2-yl) Malonate Derivatives towards 4H-Dihydroquinolizines Locquet, P.; Boussalem, N.; Hatey, D.; Grellepois, F.; H\u00e9non, E.; Riguet, E.; Blanc, A. 2026, Org. Lett., ASAP. Pre-Print: 10.26434\/chemrxiv-2025-2p3qw 2025 Synergistic Gold-Silicon Catalysis: Unravelling Alkynyl Gold Reactivity and Application to the High-Performance C-Alkynylation of Glycals Pascaretti, M; Starck, E.; Padilla Hernandez, A.; Pertschi, R, […]<\/p>\n","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-1209","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/cosys.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/pages\/1209","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/cosys.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/cosys.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/cosys.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/cosys.chimie.unistra.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1209"}],"version-history":[{"count":391,"href":"https:\/\/cosys.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/pages\/1209\/revisions"}],"predecessor-version":[{"id":3762,"href":"https:\/\/cosys.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/pages\/1209\/revisions\/3762"}],"wp:attachment":[{"href":"https:\/\/cosys.chimie.unistra.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1209"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}